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Currently you are able to watch "Madam Secretary - Season 4" streaming on Netflix, Netflix basic with Ads or buy it as download on Amazon Video, Apple TV, Fandango At Home.
In the 4th season of Madam Secretary Elizabeth tries to achieve diplomacy despite many global enemies poised against her and new political rivals at home. Henry takes on a new role at the CIA, which sometimes puts him at cross-purposes with Elizabeth, both professionally and personally.