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Currently you are able to watch "Madam Secretary - Season 2" streaming on Netflix, Netflix basic with Ads or buy it as download on Amazon Video, Apple TV, Fandango At Home.
The 2nd season of Madam Secretary begins with the kidnapping of a State Department employee and the disappearance of Russian President, Pavel Ostrov. Meanwhile, Henry gets back into the spy game and Stevie faces a difficult decision about her relationship with Harrison.