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Currently you are able to watch "Madam Secretary - Season 1" streaming on Netflix, Netflix basic with Ads or buy it as download on Amazon Video, Apple TV, Fandango At Home.
Tea Leoni stars as Elizabeth McCord, the shrewd, determined, newly appointed Secretary of State who drives international diplomacy, battles office politics and circumvents protocol as she negotiates global and domestic issues, both at the White House and at home.