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Currently you are able to watch "Catherine the Great - Season 1" streaming on The Roku Channel, Freevee for free with ads or buy it as download on Amazon Video.
"Catherine The Great" is the story of the great Russian empress in her early years, a prelude to her rise of power. Prepare to become a witness of the first 20 years (1744-1762) of her life in Russia. 20 years of court intrigues, conspiracies, power struggles and un-conditional love for her country. Russian series with English subtitles.