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You are able to buy "Valentine's Day" on Apple TV as download.
There are no options to watch Valentine's Day for free online today in Australia. You can select 'Free' and hit the notification bell to be notified when show is available to watch for free on streaming services and TV.
Valentine's Day is a 1964 comedy television series that appeared on ABC's schedule. The series starred Tony Franciosa as Valentine Farrow, a swinging Manhattan publishing executive, and Jack Soo, later of Barney Miller as Rocky Sin, Farrow's poker-playing con-artist valet. The show was created by Hal Kanter and lasted only one season. One noteworthy episode was produced as a tie-in to the movie Rio Conchos, in which Franciosa co-starred; he played both Valentine and his Mexican character from the feature.