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You are able to buy "Scorpion - Season 4" on Apple TV as download.
Eccentric genius Walter O'Brien and his team of brilliant misfits continue to be the last line of defense against the complex, high-tech threats of the modern age as they solve extreme, life-threatening cases, including a global extinction event, a nuclear missile launch on U.S. soil, and even the perils of geniuses trying to start a family.