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You are able to buy "Scorpion - Season 1" on Apple TV as download.
There are no options to watch Scorpion for free online today in Australia. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
Scorpion is a high-octane thill ride based on the true story of Walter O'Brien, an eccentric genius with the world's fourth-highest I.Q. and the creator of a company of brilliant misfits who use their mental muscle to defend the planet against complex high-tech threats of the modern age.