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You are able to buy "Psychoville - Season 1" on Apple TV as download.
There are no options to watch Psychoville for free online today in Australia. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
A chilling message draws five seemingly disparate characters into a dark tale of blackmail and desire in this cliff-hanging comedy from the creators of The League of Gentlemen. After receiving an ominous message from a mysterious writer, the five are forced to confront their past and the secret that binds them together.