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Currently you are able to watch "Arrow - Season 3" streaming on Amazon Prime Video or buy it as download on Fetch TV, Apple TV.
Arrow is available to watch for free today. If you are in Australia, you can:
Having achieved true hero status - Oliver Queen faces new challenges with a foe who has come back from the dead. This time, he has help in the form a new hero/side kick and a lot of familiar faces. There is also a new player - Ray Palmer (future atom) - in the mix, who has a new vision for turning Starling City into Star City.