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Currently you are able to watch "Mr. & Mrs. Smith - Season 1" streaming on Amazon Prime Video.
Mr. & Mrs. Smith is available to watch for free today. If you are in India, you can:
Nominated for 16 Emmy® Awards including Outstanding Drama Series – Meet the Smiths: two lonely strangers, John and Jane, who have given up their lives and identities to be thrown together as partners – both in espionage and in marriage.