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Currently you are able to watch "Smallville - Season 6" streaming on Amazon Prime Video, Amazon Prime Video with Ads or buy it as download on Apple TV.
There are no options to watch Smallville for free online today in Canada. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
Clark manages to escape from the Phantom Zone with the help of an unexpected ally. He subsequently sets out on a mission to hunt down the dangerous prisoners who followed him to Earth. Adding to Clark's troubles, there is a new vigilante in town who goes by the name Green Arrow. Meanwhile, Lex and Lana take the next step in their relationship. As the season progress, the rivalry between Clark Kent and Lex Luthor will explode into a fierce good-versus-evil battle.