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Currently you are able to watch "Smallville - Season 4" streaming on Amazon Prime Video, Amazon Prime Video with Ads or buy it as download on Apple TV.
Smallville is available to watch for free today. If you are in Canada, you can:
Clark Kent will have plenty of reasons to remember his senior year! Lois Lane — smart, opinionated and entirely annoying to Clark — arrives in Smallville to look investigate the death of her cousin. Lana gets a new older boyfriend. Clark decides to go against his parents' wishes and joins the football team as a quarterback. And while Clark sets off on a quest to to find three mysterious Kryptonian crystals, Lex steps further from the light into darkness.