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You are able to buy "Scorpion - Season 3" on Apple TV as download.
There are no options to watch Scorpion for free online today in Canada. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
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In the third season premiere, Team Scorpion must put aside their personal and romantic troubles when anonymous hackers with unknown motives take control of targeted U.S. military aircraft and war ships and point America's weaponry at its own cities.