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You are able to buy "Hart of Dixie" on Apple TV as download.
There are no options to watch Hart of Dixie for free online today in Canada. You can select 'Free' and hit the notification bell to be notified when show is available to watch for free on streaming services and TV.
New Yorker Zoe Hart has it all figured out - after graduating top of her class from medical school, she'll follow in her father's footsteps and become a cardio-thoracic surgeon. But when her dreams fall apart, Zoe decides to work at a small practice in Bluebell, Alabama.