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Currently you are able to watch "Captain Scarlet and the Mysterons - Season 1" streaming on Tubi TV for free with ads.
Captain Scarlet and the Mysterons is available to watch for free today. If you are in Canada, you can:
2068: Earth is at war with a bizarre Martian enemy - the Mysterons. Only Spectrum the world security organisation, and its number one agent, Captain Scarlet, can hope to defend the planet against the invading aliens and stop the interglactic war of nerves before Earth is destroyed!