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You are able to buy "Arrow - Season 6" on Apple TV as download.
There are no options to watch Arrow for free online today in Canada. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
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Oliver has finally solidified and strengthened his crime-fighting team only to have it threatened when unexpected enemies from his past , including Black Siren, return to Star City, forcing Oliver to rethink his relationship with each member of his “family.” With the team left hanging in the balance, the focus shifts to the fates of every member of Team Arrow!