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You are able to buy "Scorpion - Season 4" on Apple TV as download.
There are no options to watch Scorpion for free online today in Australia. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
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Eccentric genius Walter O'Brien and his team of brilliant misfits continue to be the last line of defense against the complex, high-tech threats of the modern age as they solve extreme, life-threatening cases, including a global extinction event, a nuclear missile launch on U.S. soil, and even the perils of geniuses trying to start a family.