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You are able to buy "Peg + Cat - Season 1" on Apple TV as download.
There are no options to watch Peg + Cat for free online today in Australia. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
From PBS KIDS and The Fred Rogers Company, Peg and Cat's adventures take them through worlds of infinite possibilities -- from farms to purple planets, from 16th-century Verona to New York's Radio City Music Hall, from a land of pirates to a prehistoric valley -- demonstrating that math is everywhere.