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You are able to buy "Accidentally on Purpose - Season 1" on Apple TV as download.
There are no options to watch Accidentally on Purpose for free online today in Australia. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
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Accidentally On Purpose is a comedy starring Golden Globe Award winner Jenna Elfman as Billie, a single woman who finds herself "accidentally" pregnant after a one-night stand with a much younger guy and decides to keep the baby and the guy.