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Currently you are able to watch "Catherine the Great - Season 1" streaming on Amazon Prime Video.
"Catherine The Great" is the story of the great Russian empress in her early years, a prelude to her rise of power. Prepare to become a witness of the first 20 years (1744-1762) of her life in Russia. 20 years of court intrigues, conspiracies, power struggles and un-conditional love for her country. Russian series with English subtitles.