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Currently you are able to watch "Madam Secretary - Season 6" streaming on Sky Go or for free with ads on UKTV Play. It is also possible to buy "Madam Secretary - Season 6" as download on Amazon Video, Apple TV.
Season six of MADAM SECRETARY finds Elizabeth (Téa Leoni) newly elected as President of the United States, encountering the challenges and the splendor of America’s highest office along with First Gentleman Henry (Tim Daly) and her family.