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Currently you are able to watch "Chuck - Season 2" streaming on Amazon Prime Video or buy it as download on Blockbuster.
The second season continues to focus on Chuck's constant struggle to keep his spy life and real life apart as he becomes more accustomed to being a spy. More background on the Intersect project is revealed. Fulcrum, a hostile espionage organization that covets the Intersect, is featured more heavily as the season's main antagonist. Chuck and Sarah continue to grow closer, complicating their asset-handler relationship.