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Currently you are able to watch "A Certain Scientific Railgun" streaming on Crunchyroll Amazon Channel or buy it as download on Microsoft Store.
Misaka’s electro-manipulation abilities – and delightfully destructive Railgun projectile move – make her a rock star in Academy City. The techno-metropolis is packed with supernaturally powered students known as espers, including Misaka’s flirty friend and roommate, Kuroko. She uses her teleportation skills as a member of the Judgment law enforcement team, fighting crime alongside her fellow agent Uiharu. Joined by their friend Saten, a spunky Level 0 esper, Misaka, Kuroko, and Uiharu have a blast taking on danger whenever and wherever it arises.