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Currently you are able to watch "Smallville - Season 3" streaming on Amazon Prime Video.
Smallville is available to watch for free today. If you are in India, you can:
Everyone has a future. Clark Kent has a destiny — if he’s willing to accept it and to master all the awesome powers and responsibilities that come with it. In an event-packed third season, the fascinating reinterpretation of the Superman mythology and its classic characters continues as Clark embraces the dark side and Jonathan Kent strikes a devil’s bargain with Jor-El to rescue his son.