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Currently you are able to watch "Madam Secretary - Season 5" streaming on Amazon Prime Video, Jio Cinema.
Madam Secretary is available to watch for free today. If you are in India, you can:
Season five of Madam Secretary finds Elizabeth (Téa Leoni) and President Dalton (Keith Carradine) confronting an unexpected new enemy: homegrown violent nationalists. Also, Henry (Tim Daly) begins a new job as a White House ethics advisor, occasionally butting heads with Elizabeth over foreign policy, and Elizabeth begins the early stages of her presidential run.