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Currently you are able to watch "Chuck - Season 3" streaming on Amazon Prime Video.
In season three, Chuck finally has the potential to become a real agent. There's just one problem — his emotions. Can Chuck keep them in check as he assumes his new role as the Intersect 2.0? His handlers, Sarah Walker and John Casey, will still be there to protect him, but they also must help him become the agent he is destined to be.