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Currently you are able to watch "Arrow - Season 3" streaming on Amazon Prime Video. It is also possible to buy "Arrow - Season 3" on SF Anytime, Blockbuster as download or rent it on SF Anytime online.
Having achieved true hero status - Oliver Queen faces new challenges with a foe who has come back from the dead. This time, he has help in the form a new hero/side kick and a lot of familiar faces. There is also a new player - Ray Palmer (future atom) - in the mix, who has a new vision for turning Starling City into Star City.