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Currently you are able to watch "Arrow - Season 2" streaming on Amazon Prime Video. It is also possible to buy "Arrow - Season 2" on SF Anytime, Blockbuster as download or rent it on SF Anytime online.
At the end of Season 1, Starling city suffered a huge loss and so did Oliver Queen. Learning from his mistakes, Oliver decides to change his methods even while honouring his promises to his friend. Meanwhile a new enemy from his past resurfaces to make life difficult for Oliver.