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You are able to buy "Madam Secretary - Season 2" on Apple TV as download.
There are no options to watch Madam Secretary for free online today in Canada. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
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The 2nd season of Madam Secretary begins with the kidnapping of a State Department employee and the disappearance of Russian President, Pavel Ostrov. Meanwhile, Henry gets back into the spy game and Stevie faces a difficult decision about her relationship with Harrison.