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You are able to buy "Kings of Pain - Season 1" on Apple TV as download.
There are no options to watch Kings of Pain for free online today in Canada. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
“Kings of Pain” follows wildlife biologist Adam Thorn and professional animal handler Rob “Caveman” Alleva as they get bit and stung by some of the most dangerous animals and vicious stinging insects in the world – from a reticulated python to a rove beetle – to create a complete and comprehensive pain index that will ultimately help save lives.