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Currently you are able to watch "Demon King Daimao - Season 1" streaming on HiDive.
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Akuto Sai is a new student at Constan Magical Academy. On the day of admittance, his aptitude test predicts his future occupation as... Demon King. And so begins the trials and tribulations of school life as he is hounded by do-gooders, self appointed protectors, and overzealous followers. In this school, there's no rest for the Devil King.