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You are able to buy "Defiance - Season 1" on Apple TV as download.
There are no options to watch Defiance for free online today in Canada. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
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In the year 2046, it's a new Earth - with new rules. Over thirty years after various alien races arrived on Earth, the landscape is completely altered, terraformed nearly beyond recognition. To the town of Defiance, on what used to be St. Louis, comes the mysterious Nolan and his charge, Irisa.