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You are able to buy "Arrow - Season 3" on Apple TV as download.
There are no options to watch Arrow for free online today in Canada. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
Having achieved true hero status - Oliver Queen faces new challenges with a foe who has come back from the dead. This time, he has help in the form a new hero/side kick and a lot of familiar faces. There is also a new player - Ray Palmer (future atom) - in the mix, who has a new vision for turning Starling City into Star City.