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You are able to buy "Arrow - Season 2" on Apple TV as download.
There are no options to watch Arrow for free online today in Canada. You can select 'Free' and hit the notification bell to be notified when season is available to watch for free on streaming services and TV.
At the end of Season 1, Starling city suffered a huge loss and so did Oliver Queen. Learning from his mistakes, Oliver decides to change his methods even while honouring his promises to his friend. Meanwhile a new enemy from his past resurfaces to make life difficult for Oliver.